4-Bromophenoxybenzene

4-Bromophenoxybenzene Basic information

Product Name:	4-Bromophenoxybenzene
Synonyms:	4-BROMOPHENYL PHENYL ETHER;4-bromophenoxybenzene;4-BROMODIPHENYL OXIDE;p-phenoxybromobenzene;p-Phenoxyphenyl bromide;P-BROMODIPHENYL ETHER;P-BROMOPHENYL PHENYL ETHER;1-BROMO-4-PHENOXY-BENZENE (4-BROMOPHENYL PHENYL ETHER)
CAS:	101-55-3
MF:	C12H9BrO
MW:	249.1
EINECS:	202-952-4
Product Categories:	Alcohol& Phenol& Ethers;API intermediates;Biphenyl & Diphenyl ether
Mol File:	101-55-3.mol

4-Bromophenoxybenzene Chemical Properties

Melting point	18 °C (lit.)
Boiling point	305 °C (lit.)
density	1.423 g/mL at 25 °C (lit.)
vapor pressure	1.94 x 10^-3 mmHg at 25 °C (subcooled liquid, Tittlemier et al., 2002)
refractive index	n20/D 1.607(lit.)
Fp	>230 °F
storage temp.	2-8°C
solubility	Soluble in ether (Weast, 1986) and many other solvents including 1,4-dioxane, benzene, and toluene.
form	Liquid
color	Colorless to Almost colorless
BRN	1308972
Henry's Law Constant	2.27 at 25 °C (integrated gas-stripping method, GC, Lau et al., 2006)
Stability:	Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey	JDUYPUMQALQRCN-UHFFFAOYSA-N
CAS DataBase Reference	101-55-3(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-bromo-4-phenoxy-(101-55-3)
EPA Substance Registry System	p-Bromophenyl phenyl ether (101-55-3)

Safety Information

Hazard Codes	N,Xn,F
Risk Statements	50/53-67-65-38-11-43-41-22
Safety Statements	60-61-62-36/37/39-26-33-29-16-9
RIDADR	UN 3082 9/PG 3
WGK Germany	3
TSCA	Yes
HazardClass	9
PackingGroup	III
HS Code	29093090
Hazardous Substances Data	101-55-3(Hazardous Substances Data)
Toxicity	LC₅₀ (24-h) for Daphnia magna 0.46 mg/L (LeBlanc, 1980).

MSDS Information

Provider	Language
4-Bromophenoxybenzene	English
SigmaAldrich	English
ALFA	English

4-Bromophenoxybenzene Usage And Synthesis

Chemical Properties	light yellow liquid
Definition	ChEBI: An aromatic ether that is diphenyl ether substituted at position 4 by a bromo group.
General Description	Liquid. Freezing point 18°C. Density 1.423 g / cm3. Insoluble or slightly soluble in water.
Air & Water Reactions	Insoluble in water.
Reactivity Profile	4-Bromophenoxybenzene oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164].
Fire Hazard	Combustible.
Environmental fate	Biological. Using settled domestic wastewater inoculum, 4-bromophenyl phenyl ether (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981). Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 303, 112, 41, and 15 mg/g, respectively (Dobbs and Cohen, 1980).

4-Bromophenoxybenzene Preparation Products And Raw materials

Raw materials	TRIPHENYLSULFONIUM TRIFLUOROMETHANESULFONATE-->4-Bromophenol-->1-Bromo-4-iodobenzene-->1-Bromo-4-nitrobenzene-->Phenol
Preparation Products	Pyriproxyfen-->4-PHENOXYPHENYLBORONIC ACID-->4-Phenoxyaniline-->1,4-Diphenoxybenzene-->4-Phenoxyphenol-->4-(4-BROMO-PHENOXY)-BENZENESULFONYL CHLORIDE

2,2?3-TRIBROMODIPHENYL ETHER 2,2?4,4?5,5'-HEXABROMODIPHENYL ETHER 2,2?3,3?4,5,6-HEPTABROMODIPHENYL ETHER 2,2',3,3',4,5,5',6,6'-NONABROMODIPHENYL ETHER 2,2?3,3?4,4?HEXABROMODIPHENYL ETHER 2,2',4,5'-TETRABROMODIPHENYL ETHER 2,5-DIBROMODIPHENYL ETHER 2,3,3',4,4',5,6-HEPTABROMODIPHENYL ETHER 2,2',3,3',4,5,5',6,-OCTABROMODIPHENYL ETHER 2,3,5-TRIBROMODIPHENYL ETHER 2,2?4,4?5,6'-HEXABROMODIPHENYL ETHER PBDES STANDARD SOLUTION FOR ACCURACY & PRECISION 3,3?,4,4?-TETRABROMODIPHENYL ETHER 2,6-DIBROMODIPHENYL ETHER 2-BROMODIPHENYL ETHER 2,2?4,4?6,6?HEXABROMODIPHENYL ETHER 13C-BROMINATED DIPHENY ETHER SOLN 3,5-DIBROMODIPHENYLETHER

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