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| Product Name: | LEAD(II) THIOCYANATE | | Synonyms: | PLUMBOUS THIOCYANATE;isothiocyanicacid,lead(2+)salt;lead(ii)thiocyanate(pb(ncs)2);leaddithiocyanate;leadisothiocyanate;Leadsulfocyanate;leadthiocyanate(pb(scn)2);Thiocyanicacid,lead(2+)salt | | CAS: | 592-87-0 | | MF: | C2N2PbS2 | | MW: | 323.36 | | EINECS: | 209-774-6 | | Product Categories: | | | Mol File: | 592-87-0.mol |  |
| | LEAD(II) THIOCYANATE Chemical Properties |
| Melting point | 190 °C (dec.)(lit.) | | density | 3.82 g/mL at 25 °C(lit.) | | solubility | cold water: soluble200 part(lit.) | | form | white-yellow powder | | Specific Gravity | 3.82 | | Water Solubility | soluble ~200 parts cold, 50 parts boiling H2O [MER06]; g/L H2O: 0.0137 (18°) [KRU93] | | Merck | 14,5426 | | Solubility Product Constant (Ksp) | pKsp: 4.7 | | BRN | 3687984 | | CAS DataBase Reference | 592-87-0(CAS DataBase Reference) | | EPA Substance Registry System | Lead(II) thiocyanate (592-87-0) |
| | LEAD(II) THIOCYANATE Usage And Synthesis |
| Description | It has many applications such as phosphorus-free matches, dyeing, and explosives, especially an ingredient in primes for cartridges. Moreover, this chemical can also act as an effective agent for enhancing the performance of perovskite solar cells. For example, planar perovskite solar cells exhibit a reduced hysteresis and boosted fill factor after introducing lead thiocyanate additive.1 Using this additive, the improved performance is further verified in the formamidinium and cesium lead triiodide perovskite solar cells.2 In addition, antigen retrieval can be realized by microwave irradiation in lead thiocyanate.3 Besides, an efficient stereoselective 1,2-dithiocyanation of various alkynes has been accomplished by employing this chemical as a reagent.4
| | Reference |
- Ke, W. J.; Xiao, C. X.; Wang, C. L.; Saparov, B.; Duan, H. S.; Zhao, D. W.; Xiao, Z. W.; Schulz, P.; Harvey, S. P.; Liao, W. Q.; Meng, W. W.; Yu, Y.; Cimaroli, A. J.; Jiang, C. S.; Zhu, K.; Al-Jassim, M.; Fang, G. J.; Mitzi, D. B.; Yan, Y. F., Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells. Adv. Mater. 2016, 28, 5214-+.
- Yu, Y.; Wang, C. L.; Grice, C. R.; Shrestha, N.; Chen, J.; Zhao, D. W.; Liao, W. Q.; Cimaroli, A. J.; Roland, P. J.; Ellingson, R. J.; Yan, Y. F., Improving the Performance of Formamidinium and Cesium Lead Triiodide Perovskite Solar Cells using Lead Thiocyanate Additives. Chemsuschem 2016, 9, 3288-3297.
- Momose, H.; Mehta, P.; Battifora, H., ANTIGEN RETRIEVAL BY MICROWAVE IRRADIATION IN LEAD THIOCYANATE COMPARISON WITH PROTEASE DIGESTION RETRIEVAL. Lab. Invest. 1993, 68, A139-A139.
- Prakash, O.; Sharma, V.; Batra, H.; Moriarty, R. M., (Dichloroiodo)benzene and lead(II) thiocyanate as an efficient reagent combination for stereoselective 1,2-dithiocyanation of alkynes. Tetrahedron Lett. 2001, 42, 553-555.
| | Chemical Properties | White to yellow powder | | Chemical Properties | Leadthiocyanateisawhiteorlightyellow,odorless,
crystalline powder. Odorless | | Uses | Reverse dyeing with aniline black; manufacture of safety matches and cartridges. | | Uses | Lead (II) thiocyanate can be used:
- To form a complex with Schiff-base lariat crown ether,?N,N′-bis(3-(salicylaldimino)benzyl)-4,13-diaza-18-crown-6.
- To investigate complexing and fluorescence properties of calixarene bearing two dansyl fluorophores grafted on a large pore mesoporous silica material.
- As a reagent in the 1,2-dithiocyanation of alkynes in the presence of (dichloroiodo)benzene.
- As a precursor to synthesize perovskite films for solar cell applications.
| | General Description | A white to yellow crystalline solid. Slightly soluble in water and denser than water. Primary hazard is threat to the environment. Immediate steps should be taken to limit spread to the environment. Used to make explosives, safety matches, and in dyeing. | | Air & Water Reactions | Slightly soluble in water. | | Reactivity Profile | Nitric acid violently oxidized a thiocyanate solution [Bretherick 1979. p. 121]. Caution should be exercised in treating a thiocyanate with an oxidizing agent such as a peroxide or chlorate as such mixtures have been known to explode. May be thermally unstable. Special Hazards of Combustion Products: Irritating sulfur dioxide gas may form in fire [USCG, 1999]. | | Health Hazard | Early symptoms of lead intoxication via inhalation or ingestion are most commonly gastrointestinal disorders, colic, constipation, etc.; weakness, which may go on to paralysis, chiefly of the extensor muscles of the wrists and less often of the ankles, is noticeable in the most serious cases. Ingestion of a laarge amount causes local irritation of the alimentary tract; pain, leg cramps, muscle weakness, paresthesias, depression, coma, and death may follow in 1 or 2 days. Contact causes irritation of eyes and mild irritation of skin. | | Fire Hazard | Special Hazards of Combustion Products: Irritating sulfur dioxide gas may form in fire. | | Potential Exposure | An explosive, thermally
unstable material. Used in making safety matches, primers
for small arms cartridges; pyrotechnic devices; and in dyes. | | Shipping | UN2291 Lead compounds, soluble n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical
Name Required | | Incompatibilities | Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, and epoxides. Contact with acids or
acid fumes caused decomposition with fumes of cyanide.
Will decompose in hot water. |
| | LEAD(II) THIOCYANATE Preparation Products And Raw materials |
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