ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium 3-FLUOROPHENYLMAGNESIUM BROMIDE

3-FLUOROPHENYLMAGNESIUM BROMIDE

3-FLUOROPHENYLMAGNESIUM BROMIDE Basic information
Product Name:3-FLUOROPHENYLMAGNESIUM BROMIDE
Synonyms:3-Fluorophenylmagnesium bromide solution 1.0 in THF;3-Fluorophenylmagnesium bromide solution 0.5 in THF;3-Fluorophenylmagnesium bromide, 1M solution in THF, AcroSeal;3-FLUOROPHENYLMAGNESIUM BROMIDE;3-FLUOROPHENYLMAGNESIUM BROMIDE, 0.5M SOLU TION IN TETRAHYDROFURAN;3-FLUOROPHENYLMAGNESIUM BROMIDE, 1.0M SO;3-Fluorophenylmagnesium bromide, 1M in MeTHF;3-Fluorophenylmagnesium bromide, 0.5M in THF
CAS:17318-03-5
MF:C6H4BrFMg
MW:199.3
EINECS:
Product Categories:Grignard Reagent;Aryl;Grignard Reagents;Organometallic Reagents
Mol File:17318-03-5.mol
3-FLUOROPHENYLMAGNESIUM BROMIDE Structure
3-FLUOROPHENYLMAGNESIUM BROMIDE Chemical Properties
Boiling point 65 °C
density 1.024 g/mL at 25 °C
Fp <1 °F
storage temp. 2-8°C
Water Solubility It reacts violently with water.
Sensitive Air & Moisture Sensitive
CAS DataBase Reference17318-03-5
Safety Information
Hazard Codes F,C
Risk Statements 11-14-19-34-22-40-37
Safety Statements 16-26-33-36/37/39-45-7/8-43
RIDADR UN 2924 3/PG 2
WGK Germany 1
HazardClass 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
3-FLUOROPHENYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesColorless to yellow to orange to brown liquid
Uses3-Fluorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
Uses3-Fluorophenylmagnesium bromide is a Grignard reagent that can be used in:
  • The preparation of 4-substituted quinazolines by reacting with 2-methylaminobenzonitriles.
  • The synthesis of radiolabeled TrkB/C-targeting kinase inhibitor for positron emission tomography (PET) imaging applications.
  • Cu-catalyzed carbometalation of substituted cyclopropenes.

3-FLUOROPHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation Products3-Fluorostyrene-->3-FLUOROPHENYLACETYLENE-->Carbamic acid, N-[4-(3-fluorophenyl)-4-oxobutyl]-, 1,1-dimethylethyl ester-->4-(3-FLUOROPHENYL)-4-OXOBUTYRIC ACID-->2-fluoro-1-(3-fluorophenyl)ethanone
4-FLUOROPHENYLMAGNESIUM BROMIDE, 2M IN DIETHYL ETHER,4-FLUOROPHENYLMAGNESIUM BROMIDE 3-FLUOROPHENYLMAGNESIUM BROMIDE 3-FLUORO-2-METHYLPHENYLMAGNESIUM BROMIDE 3-CHLORO-5-FLUOROPHENYLMAGNESIUM BROMIDE 3,5-DIFLUOROPHENYLMAGNESIUM BROMIDE PHENYLMAGNESIUM BROMIDE 3-FLUORO-2-METHYLPHENYLMAGNESIUM BROMID& 3-CHLORO-4-FLUOROPHENYLMAGNESIUM BROMIDE 3,4-DIFLUOROPHENYLMAGNESIUM BROMIDE 5-FLUORO-2-METHYLPHENYLMAGNESIUM BROMIDE 3 4 5-TRIFLUOROPHENYLMAGNESIUM BROMIDE 2-FLUORO-4-BIPHENYLMAGNESIUM BROMIDE 5-FLUORO-2-METHOXYPHENYLMAGNESIUM BROMIDE PENTAFLUOROPHENYLMAGNESIUM BROMIDE 3-FLUORO-4-METHOXYPHENYLMAGNESIUM BROMIDE 4-(1,3-DIOXAN-2-YL)-3-FLUOROPHENYLMAGNESIUM BROMIDE 3-(1,3-DIOXAN-2-YL)-4-FLUOROPHENYLMAGNESIUM BROMIDE 4-CHLORO-3-FLUOROPHENYLMAGNESIUM BROMIDE
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