DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II)

DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Basic information
Product Name:DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II)
Synonyms:DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II);Dichloro[1,3-bis(2,6-diisopropylphenyl)imidazolyl-2-idene](3-chloropyridyl)palladium(IV);[1,3-Bis(2,6-Diisopropylphenyl)iMidazol-2-ylidene](3-chloropyridyl)palladiuM(II) dichloride,98% PEPPSI-IPr catalyst;PEPPSI(TM)-IPr catalyst 98%;[1,3-Bis(2,6-Diisopropylphe;1,3-bis(2,6-diisopropylphenyl)-2H-imidazole;[1,3-Bis(2,6-diisopropylphenyl)imidazol-2(3H)-ylidene](3-chloro-1-pyridyl)palladium(IV) Chloride;DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) ISO 9001:2015 REACH
CAS:905459-27-0
MF:PEPPSI-IPr
MW:0
EINECS:
Product Categories:Pd
Mol File:905459-27-0.mol
DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Structure
DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Chemical Properties
Melting point 240℃ (DEC.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form powder
color Beige
CAS DataBase Reference905459-27-0
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
WGK Germany 3
HS Code 28439000
MSDS Information
DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Usage And Synthesis
DescriptionPEPPSI-IPr catalyst ([1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride) with the CAS number of 905459-27-0 is an organometallic palladium?catalyst?for numerous cross-coupling reactions including Kumada-Tamao-Corriu (KTC), Buchwald-Hartwig amination, Suzuki coupling, and Negishi coupling.It is usually in the forms of white to yellow and grey black powder, and it is air sensitive with the shelf life of 12 month.
Chemical PropertiesYellow crystal
Uses
  • Catalyst for Kumada-Tamao-Corriu (KTC) reaction (eq. 1)
  • Catalyst for Negishi coupling reaction (eq. 2)
  • Catalyst for Suzuki coupling reaction (eq. 3)
  • Catalyst for Buchwald-Hartwig amination reaction (eq. 4)
UsesCatalyst for Kumada-Tamao-Corriu (KTC) reaction (eq. 1) Catalyst for Negishi coupling reaction (eq. 2) Catalyst for Suzuki coupling reaction (eq. 3) Catalyst for Buchwald-Hartwig amination reaction (eq. 4) TM -IPr catalyst.
DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Preparation Products And Raw materials
Methylisothiazolinone 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Diisopropylammonium dichloroacetate (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE GRUBBS CATALYST 2ND GENERATION N,N-Diisopropylethylamine Diisopropylamine DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)-2-IMIDAZOLIDINYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Diisopropyl ether Ruthenium(III) chloride hydrate(1:x)

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