Phenyl phosphine

Phenyl phosphine Basic information
Product Name:Phenyl phosphine
Synonyms:Phenylphosphine ca. 10% weight in hexanes;Phenylphosphine, 99% (Sure/Seal TM bottle);Phenylphosphine (Sure/Seal bottle);AURORA KA-1101;Phosphaniline;Fenylfosfin;Phenylphosphine,99%(10wt%inhexane);Phenylphosphine,99%(Sure/Sealbottle)
CAS:638-21-1
MF:C6H7P
MW:110.09
EINECS:211-325-4
Product Categories:organophosphorus ligand;organophosphine ligand;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
Mol File:638-21-1.mol
Phenyl phosphine Structure
Phenyl phosphine Chemical Properties
Melting point 148-151 °C
Boiling point 160°C
density 1.001
vapor density 3.79 (vs air)
vapor pressure 760 mmHg ( 160 °C)
refractive index 1.578
Fp -20°F
storage temp. -20°C
form liquid
color colorless
Water Solubility Insoluble in water.
Sensitive Air & Moisture Sensitive
BRN 741946
Exposure limitsACGIH: Ceiling 0.05 ppm
NIOSH: Ceiling 0.05 ppm(0.25 mg/m3)
InChIKeyRPGWZZNNEUHDAQ-UHFFFAOYSA-N
CAS DataBase Reference638-21-1(CAS DataBase Reference)
NIST Chemistry ReferencePhenylphosphine(638-21-1)
EPA Substance Registry SystemPhenylphosphine (638-21-1)
Safety Information
Hazard Codes F;T;N,N,T,F,Xn
Risk Statements 11-17-23/24/25-36/37/38-48/20-51/53-62-65-67-38-20/21/22
Safety Statements 16-26-36/37/39-45-62-61-36/37
RIDADR 2924
WGK Germany 3
RTECS SZ2100000
HazardClass 4.2
PackingGroup I
Hazardous Substances Data638-21-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Phenyl phosphine English
ALFA English
Phenyl phosphine Usage And Synthesis
Chemical PropertiesPhenylphosphine is a clear, colorless liquid. Foul odor.
UsesIt is mainly used as a precursor to other organophosphorus compounds. It can function as a?ligand?in coordination chemistry. Phenylphosphine also have uses in polymer synthesis.
UsesExposure to phenylphosphine may occur when phenylphosphinates (used as catalysts and antioxidants) are heated above 200°C, yielding phenylphosphonic acid derivatives and phenylphosphine.
Usessuzuki reaction
General DescriptionClear colorless liquid.
Air & Water ReactionsPyrophoric in air. Insoluble in water. Slowly generates flammable or noxious gases in contact with water.
Reactivity ProfilePhenyl phosphine is a reducing agent. They slowly generate flammable or noxious gases in contact with water. Phosphides react quickly upon contact with moisture or acids to give the very toxic gas phosphine; phosphides also can react vigorously with oxidizing materials. In general, materials in this group are incompatible with oxidizers such as atmospheric oxygen. They are violently incompatible with acids, particularly oxidizing acids.
Health HazardPhenylphosphine is a respiratory and skin irritant; multiple exposures in rodents causes hematologic changes and testicular degeneration in males.
Fire HazardFlash point data are not available for Phenyl phosphine, but Phenyl phosphine is probably combustible.
Safety ProfilePoison by inhalation. Igmtes spontaneously in air. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHINE.
Potential ExposurePolyphosphinate is used as an intermediate or a chemical reagent. Polyphosphinate compounds are used as catalysts and antioxidants disproportionate, when heated to give phosphonic acid derivatives plus PF.
ShippingUN2845 Pyrophoric liquids, organic, n.o.s Hazard Class: 4.2, Labels: 4.2-Spontaneously combustible material. Technical Name Required. Note: this chemical is also a strong reducing agent.
IncompatibilitiesA strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Water reactive; spontaneously combustible in high concentrations in moist air. Potential exposure to gaseous phenylphosphine and phosphorus oxides when heated above 200C. Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Chlorodimethylphenylsilane Diphenylphosphinic acid 1,4-Bis(diphenylphosphino)butane 1,1'-Bis(diphenylphosphino)ferrocene Lactulose diphenylphosphine [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 1,3-Bis(diphenylphosphino)propane 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Phenylphosphonic dichloride Chlorodiphenylphosphine PHENYL VALERATE 1,2-Bis(diphenylphosphino)ethane Dichlorophenylphosphine (4-bromophenyl)diphenylphosphine BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE (CYCLOPENTADIENYLIDENE)TRIPHENYLPHOSPHORANE Phenylacetic acid

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