(S)-(+)-Epichlorohydrin

(S)-(+)-Epichlorohydrin Basic information

Product Name:	(S)-(+)-Epichlorohydrin
Synonyms:	(S)-(+)-2-(Chloromethyl)oxirane (S)-Epichlorohydrin (S) 1-Chloro-2,3-epoxypropane (S)-3-Chloropropylene Oxide (S)-Chloromethyloxirane (S)-(+)-1-Chloro-2,3-epoxypropane 2-(Chloromethyl)oxirane;(S)-(+)-CHLOROMETHYLOXIRANE;(S)-CHLOROMETHYLOXIRANE;(S)-3-CHLOROPROPYLENE OXIDE;S(+)-2-(CHLOROMETHYL)OXIRANE;(S)-(+)-1-CHLORO-2,3-EPOXYPROPANE;(S)-1-CHLORO-2,3-EPOXYPROPANE;OXIRANE, (CHLOROMETHYL)-, (2S)-
CAS:	67843-74-7
MF:	C3H5ClO
MW:	92.52
EINECS:	614-150-5
Product Categories:	Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Oxiranes;Simple 3-Membered Ring Compounds;Synthetic Organic Chemistry;Chiral Compound;Industrial/Fine Chemicals;chiral;CHIRAL COMPOUNDS;Chiral Reagents;Heterocycles;Mutagenesis Research Chemicals;Heterocyclic Acids;67843-74-7
Mol File:	67843-74-7.mol

(S)-(+)-Epichlorohydrin Chemical Properties

Melting point	−57 °C(lit.)
Boiling point	92-93 °C360 mm Hg(lit.)
alpha	34 º (589nm, c=1, MeOH)
density	1.183 g/mL at 25 °C(lit.)
vapor density	3.2 (vs air)
vapor pressure	13.8 mm Hg ( 21.1 °C)
refractive index	n20/D 1.438(lit.)
Fp	93 °F
storage temp.	Inert atmosphere,2-8°C
solubility	Chloroform, Methanol (Slightly)
form	Liquid
color	Clear colorless to very pale yellow
optical activity	[α]20/D +35°, c = 1 in methanol
explosive limit	21%
Water Solubility	insoluble
BRN	1420784
CAS DataBase Reference	67843-74-7(CAS DataBase Reference)

Safety Information

Hazard Codes	T
Risk Statements	45-10-23/24/25-34-43
Safety Statements	53-45
RIDADR	UN 2023 6.1/PG 2
WGK Germany	3
RTECS	TX4900000
Autoignition Temperature	1421 °F
HazardClass	6.1
PackingGroup	II
HS Code	29038900

MSDS Information

Provider	Language
(S)-(+)-Epichlorohydrin	English
SigmaAldrich	English
ACROS	English
ALFA	English

(S)-(+)-Epichlorohydrin Usage And Synthesis

Chemical Properties	Colorless to light yellow liqui
Chemical Properties	Epichlorhydrin is a colourless liquid with odour, b.p. 115°C.
Uses	S-enantiomer of Epichlorohydrin, (S)-Epichlorohydrin), an important industrial chemical, is a bifunctional alkylating agent with the potential to form DNA cross-links. It is used as a solvent for natural and synthetic resins, gums, cellulose esters and ethers, paints, varnishes, nail enamels and lacquers, cement for Celluloid. Also, it is used as stabilizer.
Uses	(S)-(+)-Epichlorohydrin is utilized for the synthesis of macquarimicins and hydroxyisoxazolidines and (+)-cis-sylvaticin, which is a potential antitumor agent. It is used to synthesize inhibitors of fatty acid oxidation as potential metabolic modulators. It acts as a solvent for natural and synthetic resins, gums, cellulose esters and ethers, paints, varnishes, nail enamels, lacquers and cement for celluloid. It is also used as a stabilizer and also useful as a bifunctional alkylating agent with the potential to form DNA cross-links.
Definition	ChEBI: (S)-epichlorohydrin is an epichlorohydrin. It is functionally related to a (R)-1,2-epoxypropane. It is an enantiomer of a (R)-epichlorohydrin.

(S)-(+)-Epichlorohydrin Preparation Products And Raw materials

Raw materials	(S)-(+)-3-Chloro-1,2-propanediol-->(R)-(-)-3-Chloro-1,2-propanediol-->(R)-(-)-Epichlorohydrin-->Epichlorohydrin
Preparation Products	(S)-4-Chloro-3-hydroxybutyronitrile-->(+)-1-(tert-butylamino)-3-[(4-morpholino-1,2,5-thiadiazol-3-yl)oxy]propan-2-ol-->(S)-2-Oxiranylanisole-->DIGLYCIDYL ETHER-->Morpholine, 4-[(2R)-oxiranylmethyl]- (9CI)

Fatty acids, tall-oil, reaction products with bisphenol A, epichlorohydrin, glycidyl tolyl ether and triethylenetetramine Hexanedioic acid, polymer with N-(2-aminoethyl)-1,2-ethanediamine, N-(1-oxohexyl) derivs., epichlorohydrin-quaternized epichlorohydrin Chloromethyl methyl ether Resin epoxy ETHYLENE OXIDE Epichlorohydrin rubber Fatty acids, dehydrated castor-oil, reaction products with bisphenol A-epichlorohydrin polymer and soya fatty acids Difluorochloromethane EPICHLOROHYDRIN (13C3, 99%) 100 UG/ML IN ACETONITRILE Z-3-Chloro-1-(2-chlorophenyl)-2-(4-fluorophenyl)-oxirane (S)-(+)-Epichlorohydrin Cashew, nutshell liq., polymer with epichlorohydrin and phenol Fatty acids, C16 and C18-unsatd., polymers with bisphenol A, Bu glycidyl ether, epichlorohydrin and triethylenetetramine Epichlorohydrin (R)-(-)-EPICHLOROHYDRIN 99% (+)-TRANS-HEPTACHLOREPOXIDE Propylene oxide

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