ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon halides 3-Bromobenzyl bromide

3-Bromobenzyl bromide

3-Bromobenzyl bromide Basic information
Product Name:3-Bromobenzyl bromide
Synonyms:3-Brombenzyl bromide;ALPHA,3-DIBROMOTOLUENE;ALPHA,M-DIBROMOTOLUENE;3-BROMOBENZYL BROMIDE;3-Bromo Benzyl Bromide m-Bromobenzyl Bromide;3-BromobenzylBromide98%;3-Bromobenzylbromide,99%;m-Bromobenzyl
CAS:823-78-9
MF:C7H6Br2
MW:249.93
EINECS:212-519-1
Product Categories:alkyl bromide;Benzyl;Aromatic Halides (substituted);bc0001
Mol File:823-78-9.mol
3-Bromobenzyl bromide Structure
3-Bromobenzyl bromide Chemical Properties
Melting point 39-41 °C(lit.)
Boiling point 130 °C12 mm Hg
density 1,56 g/cm3
refractive index 1.6066 (estimate)
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), Methanol (Slightly)
form Adhering Crystals or Crystalline Powder
color White
Water Solubility Insoluble in water.
BRN 2078683
InChIKeyZPCJPJQUVRIILS-UHFFFAOYSA-N
CAS DataBase Reference823-78-9(CAS DataBase Reference)
EPA Substance Registry SystemBenzene, 1-bromo-3-(bromomethyl)- (823-78-9)
Safety Information
Hazard Codes C
Risk Statements 34-37
Safety Statements 26-36/37/39-45-25
RIDADR UN 3261 8/PG 2
WGK Germany 3
F 19
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29036990
MSDS Information
ProviderLanguage
3-Bromobenzyl bromide English
ACROS English
SigmaAldrich English
ALFA English
3-Bromobenzyl bromide Usage And Synthesis
Chemical PropertiesWhite to yellow solid
Uses3-Bromobenzyl bromide was used in the synthesis of, 1,7-di(3-bromobenzyl)cyclen and substituted 8-arylquinoline, phosphodiesterase 4 (PDE4) inhibitors.
Uses3-Bromobenzyl bromide was used in the synthesis of:
  • 1,7-di(3-bromobenzyl)cyclen
  • substituted 8-arylquinoline, phosphodiesterase 4 (PDE4) inhibitors
General Description3-Bromobenzyl bromide undergoes reduction with diethylzinc in the presence of Pd(PPh3)4 to yield corresponding hydrocarbon.
3-Bromobenzyl bromide Preparation Products And Raw materials
Preparation ProductsButylamine Hydrobromide-->4-bromo-2-(bromomethyl)-1-nitrobenzene-->(3-BROMOBENZYL)METHYLAMINE-->3-Bromostyrene-->3-Bromobenzylamine-->3-Bromobenzyl alcohol-->1-(3-BROMOBENZYL)-1H-INDOLE-3-CARBALDEHYDE-->Acetic acid, 2-[[(3-bromophenyl)methyl]sulfonyl]--->diethyl (acetylamino)(3-bromobenzyl)malonate-->[(3-bromobenzyl)sulfanyl]acetic acid
3-Bromotoluene 3,5-Dibromobenzyl bromide 2-FLUORO-4-BROMOBENZYL BROMIDE,2-fluor-4-bromobenzyl bromide 3-Chlorobenzyl chloride BRETYLIUM TOSYLATE Clidinium bromide 2-Fluoro-5-bromobenzyl bromide Sodium bromate 5-FLUORO-2-BROMOBENZYL BROMIDE 3-Bromobenzyl bromide 3-Bromonitrobenzene Ethidium bromide 4-METHYL-2,3,5,6-TETRAFLUOROBENZYL BROMIDE 2-Bromobenzyl bromide Methyl bromide 3-Fluorobenzyl chloride Diethylstilbestrol 3-Bromophenol Bromobenzyl Chloride
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