5-Bromo-m-xylene

5-Bromo-m-xylene Basic information

Product Name:	5-Bromo-m-xylene
Synonyms:	m-Xylene, 5-bromo-;5-BROMO-M-XYLENE;5-BROMOMETAXYLENE;5-BROMO-M-XYLENE 98%;5-Bromo-m-xylene,98%;5-BROMO-3,5-DIMETHYLBENZENE;1-Bromo-3,5-dimethylbenzene 98%;5-BROMO-M-XYLENE, 97+%
CAS:	556-96-7
MF:	C8H9Br
MW:	185.06
EINECS:	629-686-5
Product Categories:	Aryl;Building Blocks;C8;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;alkyl bromide;Miscellaneous;Bromine Compounds;Benzene derivates;Halogen toluene;Aromatic Hydrocarbons (substituted) & Derivatives;bc0001
Mol File:	556-96-7.mol

5-Bromo-m-xylene Chemical Properties

Melting point	-20.49°C (estimate)
Boiling point	202-204 °C(lit.)
density	1.362 g/mL at 25 °C(lit.)
refractive index	n20/D 1.549(lit.)
Fp	189 °F
storage temp.	Sealed in dry,Room Temperature
solubility	Miscible with tetrahydrofuran.
form	Liquid
color	Clear colorless to light yellow
Specific Gravity	1.362
BRN	1926375
InChIKey	LMFRTSBQRLSJHC-UHFFFAOYSA-N
CAS DataBase Reference	556-96-7(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-bromo-3,5-dimethyl-(556-96-7)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38-22
Safety Statements	26-36/37/39-37/39
WGK Germany	3
Hazard Note	Irritant
HS Code	29036990

MSDS Information

Provider	Language
5-Bromo-m-xylene	English
SigmaAldrich	English
ACROS	English
ALFA	English

5-Bromo-m-xylene Usage And Synthesis

Chemical Properties	white to light yellow crystal powder
Uses	1-Bromo-3,5-dimethylbenzene has been used in the synthesis of substituted 2,2′-bis(diphenylphosphanylmethyl)-1,1′-binaphthyl derivatives.
Uses	5-Bromo-m-xylene is used in the preparation of substituted 2,2'-bis(diphenylphosphanylmethyl)-1,1'-binaphthyl derivatives. It is also used to prepare o-tolyl-3,5-xylyl ether by reacting with o-cresol. Further, it is an organic building block used in the synthesis of various chemicals as well as in the preparation of tri-o-tolylphosphine.
Uses	5-Bromo-m-xylene has been used in the synthesis of substituted 2,2′-bis(diphenylphosphanylmethyl)-1,1′-binaphthyl derivatives.
General Description	Palladium catalyzed carbon-oxygen coupling of 1-bromo-3,5-dimethylbenzene and o-cresol to potassium hydroxide to produce o-tolyl-3,5-xylyl ether has been reported.

5-Bromo-m-xylene Preparation Products And Raw materials

Preparation Products

(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE-->2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl-->TRI-M-TOLYLPHOSPHINE-->TRI-P-TOLYLPHOSPHINE-->(XYL)2P(O)H-->3,5-Dimethylbenzaldehyde-->1-Iodo-3,5-dimethylbenzene-->3-(aminomethyl)-5-bromobenzonitrile-->3,3',5,5'-TETRAMETHYLBIPHENYL-->3-Bromo-5-cyanobenzyl bromide-->METHYL 3,5-DIMETHYLBENZOATE-->BIS(3,5-DIMETHYLPHENYL)PHOSPHINE-->3-bromo-5-methylbenzoic acid-->3,5-Dimethylphenylhydrazine hydrochloride-->1-ETHYNYL-3,5-DIMETHYL-BENZENE-->2-Chloro-3',5'-dimethylbenzophenone

3-BROMO-O-XYLENE,3-Bromo-ortho-xylene,3-Bromo-o-xylene,99%,3-BROMO-O-XYLENE 99% Bromoxylenol Blue BTB Bromoxynil octanoate Musk xylene Bromoxynil 4-Bromo-2,6-dimethylphenol 4-BROMO-O-XYLENE, (3,4-DIMETHYLBROMOBENZENE). Decabromodiphenyl Ethane LABOTEST-BB LT00012623 2,4-Dimethylbromobenzene 1-AMINO-4-BROMO-2-METHYLANTHRAQUINONE 2-NITRO-4-BROMO-M-XYLENE 3-Bromo-2-Xylene 4-bromo-2-xylene Benzyldodecyldimethylammonium bromide 2-BROMO-P-XYLENE,2-Bromo-p-xylene,98+%,2-BROMO-PARA-XYLENE,2-BROMO-P-XYLENE / 1-BROMO-2,5-DIMETHYLBENZENE BCP

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