ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organic iron (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Basic information
Reactions
Product Name:(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
Synonyms:(S,S)-1,1'-BIS[(S)-ALPHA-(DIMETHYLAMINO)-PHENYLMETHYL]-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE;(R,R)-(+)-2,2'-BIS[(S)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DI(3,5-DIMETHYLPHENYL)PHOSPHINO)FERROCENE;MANDYPHOS SL-M009-2;(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE;(aS,aS)-1,1#-Bis[-(dimethylamino)benzyl]-(R,R)-2,2#-bis[di(3,5-xylyl)phos;(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene,min.97%;(s,s)-1,1'-bis[(s)-α-(dimethylamino)-phenylmethyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene (acc to cas);(αs,αs)-1,1'-bis[α-(dimethylamino)benzyl]-(r,r)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene
CAS:847997-73-3
MF:C60H64FeN2P2
MW:930.98
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;Mandyphos Series
Mol File:847997-73-3.mol
(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Structure
(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Chemical Properties
alpha +164°
form Powder
color orange
Stability:store cold
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Usage And Synthesis
Reactions
  1. Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
  2. Ligand for Rh-catalyzed hydrogenation of α- and β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3-diketones.
  3. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
  4. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
  5. Ligand for Cu-catalyzed enantioselective hydroboration of α- and β-unsaturated esters and nitriles. 
Reactions of 847997-73-3
Chemical PropertiesOrange powder
General Descriptionsold in collaboration with Solvias AG
(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Preparation Products And Raw materials
Ferrocene 1,1'-DIETHYLFERROCENE N,N-Dimethylaminomethylferrocene (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE 1,1'-Bis(diphenylphosphino)ferrocene (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE 1,1'-DIMETHYLFERROCENE (S)-(-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (ALPHAS,ALPHAS)-1,1'-BIS-[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (S)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
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