1,2-EPOXYHEXANE

1,2-EPOXYHEXANE Basic information

Product Name:	1,2-EPOXYHEXANE
Synonyms:	BUTYLOXIRAN;BUTYLOXIRANE;1-HEXENE OXIDE;1,2-HEXYLENE OXIDE;1,2-EPOXYHEXAN;1,2-EPOXYHEXANE;1,2-Hexene oxide;1,2-hexeneoxide
CAS:	1436-34-6
MF:	C6H12O
MW:	100.16
EINECS:	215-864-6
Product Categories:	Oxiranes;Simple 3-Membered Ring Compounds
Mol File:	1436-34-6.mol

1,2-EPOXYHEXANE Chemical Properties

Melting point	94°C
Boiling point	118-120 °C(lit.)
density	0.833 g/mL at 20 °C(lit.)
refractive index	n20/D 1.406
Fp	60 °F
storage temp.	2-8°C
solubility	Difficult to mix.
form	Liquid
color	Clear colorless
Specific Gravity	0.831
BRN	102568
LogP	1.950
CAS DataBase Reference	1436-34-6(CAS DataBase Reference)
EPA Substance Registry System	Oxirane, butyl- (1436-34-6)

Safety Information

Hazard Codes	F,Xn
Risk Statements	11-22-36/37/38
Safety Statements	26
RIDADR	UN 1993 3/PG 2
WGK Germany	3
RTECS	MO3630000
F	10-21
HazardClass	3
PackingGroup	III
HS Code	29109000

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

1,2-EPOXYHEXANE Usage And Synthesis

Chemical Properties	clear colorless liquid
Uses	1,2-Epoxyhexane is used as chemical reagent, organic intermediates, fine chemicals, pharmaceutical research and development.
Purification Methods	Purify it by fractional distillation through a 2ft helices-packed column at atmospheric pressure in a N2 atmosphere. [Pasto & Cumbo J Org Chem 30 1271 1965, Howarth et al. J Chem Soc 2433 1927, 13C NMR Davies & Witham J Chem Soc Perkin Trans 2 861 1975, Beilstein 17/1 V 103.]

1,2-EPOXYHEXANE Preparation Products And Raw materials

Raw materials	Diethyl ether-->Dichloromethane-->3-Chloroperoxybenzoic acid-->Peroxyacetic acid-->1-Hexene
Preparation Products	gamma-Octanoic lactone-->GLYCIDYL METHYL ETHER-->TRANS-2-HEXENE-->ethyl 3-hydroxy-heptanoate-->1-Amino-pentan-2-ol

1H,1H,2H-NONAFLUORO-1,2-EPOXYHEXANE (2S,3S)-1-Acetoxy-2,3-epoxyhexane 6H-PERFLUORO-1,2-EPOXYHEXANE HEXAMETHYLENE OXIDE 4,4,5,5,6,6,6-HEPTAFLUORO-1,2-EPOXYHEXANE 6-BROMO-1,2-EPOXYHEXANE,1-Bromo-5,6-epoxyhexane (2S,3S)-1-(Benzyloxy)-2,3-epoxyhexane (2S,3S)-1-[(tert-Butyldimethylsilyl)oxy]-2,3-epoxyhexane (2R,3R)-1-[(tert-Butyldimethylsilyl)oxy]-2,3-epoxyhexane (2R,3R)-1-(Benzyloxy)-2,3-epoxyhexane 3,4-Epoxyhexane (2R,3R)-1-Acetoxy-2,3-epoxyhexane (R)-(-)-2-METHYL 1,2-EPOXYHEXANE (2S,3S)-2,3-Epoxyhexane-1-ol (R)-(+)-1,2-EPOXYHEXANE 3,3,4,4,5,5,6,6,6-Nonafluoro-1,2-epoxyhexane S-1,2-EPOXYHEXANE

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